If you are new to Mootools, then the following tutorial will get you well grounded and running:

30 Days of Mootools 1.2 Tutorials

By the author: These tutorials will assume no previous Mootools or JavaScript experience, but will require basic knowledge of html and CSS.

What is MooTools?
From mootools.net: MooTools is a compact, modular, Object-Oriented JavaScript framework designed for the intermediate to advanced JavaScript developer. It allows you to write powerful, flexible, and cross-browser code with its elegant, well documented, and coherent API.

Combine the above tutorial with the mootools.net documentation and it makes for an excellent help:
http://mootools.net/docs/core

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